Luminescent Properties of Oxazine 170 Perchlorate Doped PMMA Fiber
نویسندگان
چکیده
The article presents fabrication and luminescent properties of poly(methyl methacrylate) (PMMA) fiber doped by Oxazine 170 perchlorate. The bright fluorescence of polymeric fiber (at molar fluorescent organic dye concentration 4.3 × 10−5) was characterized in terms of spectrum and signal attenuation vs. the fiber length. The significant changes in fluorescence spectrum (λmax red shift average slope 4.6 nm/cm and Full Width at Half Maximum (FWHM) increasing slope 6.7 nm/cm) have been noticed for the length of the fiber (0.02–0.08 m) which corresponds to a high overlapping region of absorption and emission spectra of used dye. The red shift of λmax (c.a. 80 nm) was presented in fabricated polymeric fiber at distance 0.85 m. The obtained characteristics can be used for luminescent properties optimization of fluorescent organic-dye-doped PMMA fiber.
منابع مشابه
Efficient red emission from PMMA films doped with 5,6-DTFI europium(III) complexes: synthesis, structure and photophysical properties.
A new β-diketone, 5,6-dimethoxy-2(2,2,2-trifluoroethyl)-1-indone (5,6-DTFI), has been designed and synthesized. Two series of four 5,6-DTFI Sm(3+) and Eu(3+) complexes, namely, Eu(5,6-DTFI)3(H2O)2 (1), Eu(5,6-DTFI)3(Phen) (2), Sm(5,6-DTFI)3(H2O)2 (3) and Sm(5,6-DTFI)3(Phen) (4) (Phen = 1,10-phenanthroline), have been isolated. X-ray diffraction analysis reveals that all complexes 1-4 are of mon...
متن کاملLuminescent monocyclometalated cationic gold(III) complexes: synthesis, photophysical characterization and catalytic investigations.
Stable, luminescent, and cationic monocyclometalated gold(iii) monoaryl complexes of the type [(ppy)Au(FMes)(L)](+)[OTf](-) [L = 4-phenylpyridine (), quinoline (), 4-fluoroaniline (), P(OMe)3 (), PPh3 ()], bearing different ancillary ligands, synthesized starting from the precursor complex [(ppy)Au(FMes)(OH2)](+)[OTf](-) () are reported. The preliminary assignment of the structure of the comple...
متن کاملIonic liquid as plasticizer for europium(III)-doped luminescent poly(methyl methacrylate) filmsw
Flexible luminescent polymer films were obtained by doping europium(III) complexes in blends of poly(methyl methacrylate) (PMMA) and the ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [C6mim][Tf2N]. Different europium(III) complexes have been incorporated in the polymer/ionic liquid matrix: [C6mim][Eu(nta)4], [C6mim][Eu(tta)4], [Eu(tta)3(phen)] and [choline]3[Eu(dpa...
متن کاملLu3+/Yb3+ and Lu3+/Er3+ Co-doped Antimony Selenide Nanomaterials: Synthesis, Characterization, Electrical, Thermoelectrical and Optical Properties
Lu3+/Yb3+ and Lu3+/Er3+ Co-doped Sb2Se3 nanomaterials were synthesized by a Co-reduction method in hydrothermal condition. Powder XRD patterns indicate that the LnxLn′xSb2-2xSe3 Ln: Lu3+/Yb3+ and Lu3+/Er3+ crystals (x= 0.00-0.04) are isostructural with Sb2Se3. The cell parameters were increased for compounds upon increasing the dopant content (x). SEM and TEM images show that Co-doping of Lu3+/...
متن کاملIonic liquid as plasticizer for europium(III)-doped luminescent poly(methyl methacrylate) films.
Flexible luminescent polymer films were obtained by doping europium(III) complexes in blends of poly(methyl methacrylate) (PMMA) and the ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [C(6)mim][Tf(2)N]. Different europium(III) complexes have been incorporated in the polymer/ionic liquid matrix: [C(6)mim][Eu(nta)(4)], [C(6)mim][Eu(tta)(4)], [Eu(tta)(3)(phen)] and [ch...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2017